Hanna Boström

@hannabostroem.bsky.social

Inorganic Chemist at Stockholm University. Nationally Swedish, academically British. Likes frameworks, copper, crystals, and wildlife. (she/her)

A massive thanks to the organisers involved in EPDIC for arranging such a lovely conference! I gave my first plenary (and had a great time doing so), Lara gave her first conference talk and Elina got her second poster prize. Now I just wish the trains would run as smoothly as the conference...

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I enjoyed giving a brief research talk at the WISE meeting earlier this week. Always interesting to see the very wide scope of sustainable materials science, and to interact with other researchers. Thanks to the organisers for the vibrant meeting!

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Chocolate spectroscopy! To demonstrate spectroscopy to my first-year chemistry class, especially transmittance, I passed around a bag with three types of chocolate bars during the lecture. The students were allowed to take one piece each.

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I went away a week to ECM and while I wasn't looking, the group decided to double in size! We now welcome new PhD students Nida and Qingqing and master student Katerina. During the autumn, we are also happy to host the internship students Simon and Mathias.

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Refinements are always beautiful (well, almost), but this mixed NTE/PTE* sample probably gives the most appealing set of diffraction that I have ever come across! 🔥 ❄️ *Positive thermal expansion in one direction; negative thermal expansion in the other two

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Had a great time at #MC17 organised by @rsc.org! Fun to catch up with friends and colleages, see the wonderful posters and talk, and present our work in progress. I always enjoy returning to 🏴󠁧󠁢󠁳󠁣󠁴󠁿 and of course, no Edinburgh visit is complete without a climb up Arthur's seat!

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I've done plenty of variable-pressure diffraction and (possibly) even more under variable temperature. But this weekend, I got to experience the joys of doing them both at the same time at Diamond. 💎 Please admire our (not entirely random) walk through the PT space...

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Glad to see this study out! www.doi.org/10.1039/D5DT01192B It is a metastudy of spin crossover in Hofmann complexes, as well as symmetry-mode analysis in ISODISTORT. Also lots of firsts here: my first last-author paper, first group publication, and first paper on these compounds.

Relating structure, composition, and spin crossover properties in Hofmann complexes

Spin crossover (SCO) is attractive for applications within e.g. sensing or solid-state cooling,but controlling the properties is extremely challenging. Hofmann complexes, with formulaFeLx M(CN)4 ·G (L...

doi.org

There is a new world record for negative area compressibility! A very nice and thorough study, which I had the pleasure of being a small part of 😊 doi.org/10.1021/jacs...

Colossal Negative Area Compressibility in the Ferroelastic Framework Cu(tcm)

Copper(I) tricyanomethanide, Cu(tcm), is a flexible framework material that exhibits the strongest negative area compressibility (NAC) effect ever observed─a remarkable property with potential applications in pressure sensors, artificial muscles, and shock-absorbing devices. Under increasing pressure, Cu(tcm) undergoes two sequential phase transitions (tetragonal → orthorhombic → monoclinic): It has an initial tetragonal structure (I41md) at ambient conditions, but this structure only persists within a narrow pressure range; at 0.12(3) GPa, a pressure-induced ferroelastic phase transition occurs, transforming Cu(tcm) into a low-symmetry orthorhombic structure (Fdd2). The orthorhombic phase has a NAC of −108(14) TPa–1 in the b–c plane between 0.12(3) and 0.93(8) GPa. The NAC behavior is associated with framework hinge motion in a flexible framework with “wine-rack” topology. At 0.93(8) GPa, Cu(tcm) undergoes a second phase transition and transforms into a layered monoclinic structure (Cc) with topologically interpenetrating honeycomb networks. The monoclinic phase of Cu(tcm) exhibits a slight negative linear compressibility (NLC) of −1.1(1) TPa–1 along the a axis and a zero area compressibility of Kac = Ka + Kc = 0.0(4) TPa–1 in the a–c plane over the pressure range of 0.93–2.63 GPa. In contrast to the orthorhombic phase, its mechanism is understood as the pressure-driven dampening of layer “rippling,” which acts to increase the cross-sectional area of the layer at higher hydrostatic pressures. These findings have implications for understanding the underlying mechanism of NAC phenomenon in framework materials.

doi.org