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Christian Limberg

@christianlimberg.bsky.social

Molecular inorganic chemist interested in small molecule activation/catalysis with biomimetic and surface-inspired metal complexes, associate editor of Inorganic Chemistry

18 Posts323 Follower151 Folgt
Christian Limberg@christianlimberg.bsky.social · last yr.

O2 activation at biomimetic Fe complexes/first O2-dioxygenation mediated by a Co center. onlinelibrary.wiley.com/doi/10.1002/... Great work by Kilian! Thx also to the de Visser group for fruitful collaboration, @dfg.de for funding within the research group “BioOxCat” and @humboldtuni.bsky.social

Promiscuity in Molecular Mimics of the Cysteine Dioxygenase: Effects of Selenium in the Substrate and Cobalt as the Central Metal Ion

A biomimetic model for the cysteine dioxygenase (CDO) was found to be also capable of selectively dioxygenating selenocysteamine, suggesting that the lack of reactivity found for the CDO in combinati....

onlinelibrary.wiley.com

Christian Limberg@christianlimberg.bsky.social · last yr.

Mirror, mirror at the wall, who is the fairest in small molecule activation, Mn(I) or Mg(I)? Wonderful collaboration with the Jones group, including a stay of Siad 👏 at Monash U. financed by @unisyscat.bsky.social, and the Maron group. pubs.acs.org/doi/10.1021/... #ChemSky @jacs.acspublications.org

Steric Control in Low-Valent Mn Diamide Complexes: Contrasting Magnesium and Manganese in N2 and Benzene Activation

Reduction of MnII precursors with bulky diamide ligands provided access to a complex with the longest known Mn–Mn bond and to a rare example of N2 activation at high-spin MnI centers. While some instr...

pubs.acs.org

Christian Limberg@christianlimberg.bsky.social · 2y ago

Thanks again for the nice, insightful talk! It was indeed a really pleasant day, both scientifically and on the personal basis! 🤓🤗

Gunnar Werncke@wernckelab.bsky.social · 2y ago

Had a nice, long day at the chemistry department of @humboldtuni.bsky.social. Great insights into current research by @christianlimberg.bsky.social, @braungroup.bsky.social, @joshabbenseth.bsky.social, Ray group and others. The place still feels like home although I left it more than ten year ago.

Stefanie Dehnen@stefaniedehnen.bsky.social · 2y ago

I feel extremely honored to receive this award. It is the result of a wonderful joint journey with my team and our cooperation partners. I would like to thank them all, and all the funding agencies, from the bottom of my heart! @kit.edu @dfg.de @ercresearch.bsky.social

Karlsruhe Institute of Technology (KIT)@kit.edu · 2y ago

Für herausragende Forschungsleistungen mit internationaler Resonanz auf dem Gebiet der #Chemie von #Clusterverbindungen hat die Hector Stiftung @stefaniedehnen.bsky.social mit einem Hector Wissenschaftspreis 2024 ausgezeichnet. www.kit.edu/kit/202501-h... Foto: Marco Schilling

Stefanie Dehnen
Josh Abbenseth@joshabbenseth.bsky.social · 2y ago

Excited to share our first paper of 2025 in Organometallics! 🥳 We showcase the reactivity of a geometrically constrained phosphine ligand in small molecule activation reactions. Great work by Soti! @humboldtuni.bsky.social Check it out here: 🔗 pubs.acs.org/doi/10.1021/... #chemsky #NewPI

Flash Communication: Ligand Centered Cooperative O–H Bond Splitting by a Mo(CO)5(phosphine) Complex

The synthesis and reactivity of a molybdenum carbonyl complex ligated by geometrically constrained phosphorus trisamide are reported. Reaction with potassium tert-butoxide or methanol triggers ligand...

pubs.acs.org