Dan Westervelt

@dwesty.bsky.social

Associate professor in climate change, atmospheric chemistry, and air pollution at Columbia-Lamont @lamont.columbia.edu

After work to clean up other sources of pollution in US, “big challenge” is wildfire smoke, says @dwesty.bsky.social of @lamont.columbia.edu, as exposure to high levels of air pollution over long period of time is demonstrated to lead to premature mortality. Via @wired.com. https://bit.ly/4vxTIti

How to Protect Your Health as Skies Fill With Smoke From Canada’s Wildfires

Roughly 100 fires are raging out of control in Ontario, sending smoke streaming 1,000 miles to the south and east.

wired.com

A wave of dense wildfire smoke has pushed from Michigan's Upper Peninsula to the Lower Peninsula this morning, bringing an AQI in the Purple range (Very Unhealthy) to Sault Ste. Marie. Visibility on the Mackinac Bridge is very poor, as seen in these comparison photos. Smoke coming to Detroit ~4 pm.

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NOAA's AQI model for 8 am Thu shows Brown ("Hazardous") AQI from smoke in the NYC, Detroit, Milwaukee, and Cleveland metro areas. These conditions (if they verify, remember forecasting smoke is HARD!) will likely last only for a few hours, but you don't want to be outside without an N95 mask! (7/8)

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So thrilled to see this out! 🤩 The Chemistry of Aerosol Interfaces (CHAI) model was created by the brilliant @sandhyasethuraman.bsky.social while she was an undergraduate researcher with us @mcneill-lab.org. CHAI models size-dependent kinetics in small droplets (1/4) pubs.acs.org/doi/10.1021/...

Modeling and Parametrization of Size-Dependent Processes in Multiphase Aerosol Chemistry

Many atmospherically relevant multiphase reactive systems exhibit size-dependent kinetics in laboratory studies, with apparent reaction rates increasing with decreasing droplet size, suggesting an important role for interfacial processes. Here, we present CHAI (CHemistry of Aerosol Interfaces), a physicochemical modeling framework that describes these reactive systems using an additive resistance approach, considering the various mass transfer and reaction processes taking place simultaneously in the gas phase, droplet bulk, and at the droplet surface, and their relative time scales. We demonstrate its applicability to modeling and developing parametrizations for several inorganic and organic oxidation processes in microdroplets and aerosols, including S(IV) to S(VI) conversion, through simulation of experimental data. CHAI is also used to reconcile single-droplet observations with chamber and flow tube experiments and is extended to parametrization of these processes for representation in large-scale atmospheric models. Our results show that neglecting the size dependence of aerosol reaction processes can lead to inaccuracies in atmospheric chemistry modeling, motivating the CHAI approach for modeling these multiphase reactive systems and further experimental studies.

pubs.acs.org

The article misses a key point which is that, now that the identity of these designer particles is public, it's clear they don't make much sense as an SAI material.

James Temple@jtemple.bsky.social · 3mo ago

Stardust has finally revealed its proprietary geoengineering particles are made from amorphous silica. Pre-prints here: stardustsrt.com/science It's also filed for a patent, the application for which should pop up in public records in coming days, I'm told. NYT got the scoop:

Textbook winter temperature inversion across the mid-Atlantic today impairing air quality (yellow = moderate AQI). A 20+ ºF swing in warmer temperatures today versus the last few days means warmer air aloft than at the surface (air has a lower heat capacity).

screenshot of AQI from AirNow. Green = good. Yellow = moderate. Orange = unhealthy for sensitive groups

The Trump Administration's plan to dismantle the @ncar-ucar.bsky.social is senseless & dangerous. It would weaken weather forecasting, climate research, & the science that keeps people safe. We urge that this plan be abandoned. Call Congress to #SaveNCAR today. buff.ly/7ka1BQA

Save NCAR from being dismantled today!

The Trump Administration has vowed to dissolve the center that provides critical extreme weather and climate data for our nation.

buff.ly

There has been a decent amount written thus far on the air pollution response to New York City's congestion pricing policy, most of which has been overwhelmingly positive. While PM2.5 concentrations are indeed down at most locations in NYC, (1/4)