Emilio M. Pérez

@emiliomperezlab.bsky.social

Scientist. Chemist. Nanocar racer. Research Prof. and Deputy Director @imdeananociencia.bsky.social‬. Nanotubes, 2D materials, rotaxanes, and supramolecular chemistry...mostly

I am deeply grateful for the trust placed in me to take on this challenge. My thanks to Rodolfo Miranda for bringing us this far. We are beginning work with the exceptional team @imdeanano.bsky.social to continue driving scientific excellence and innovation in the Comunidad de Madrid!

IMDEA Nanociencia@imdeanano.bsky.social · 6mo ago

El Prof. Emilio M. Pérez es nombrado nuevo director del Instituto IMDEA Nanociencia, continuando nuestra misión de impulsar la investigación de excelencia en nanociencia y nanotecnología. +info nanociencia.imdea.org/es/imdea-nan...

We have put together some ideas that we find exciting for the future of #SWCNT research: pubs.acs.org/doi/full/10..... These three C's are all over our current lines of research. Our intention here is to communicate that excitement, share ideas, and hopefully inspire other groups as well.

Chemistry, Chirality, and Complexity as Concepts in Single-Walled Carbon Nanotube Research

More than 30 years have elapsed since the description of single-walled carbon nanotubes (SWCNTs). Thirty years of intense research effort initially focused on elucidating the outstanding physical properties of SWCNTs, which gave rise to hopes for an immediate technological revolution. In parallel, advancements in synthesis and purification procedures afforded ever better samples of SWCNTs. A deeper understanding of the difficulties in exploiting the extraordinary intrinsic properties of SWCNTs and the advent of graphene marked the end of the hype. SWCNTs have now stepped out of the valley of disillusionment and are firmly climbing the slope of enlightenment. In this review, we highlight three broad concepts that we believe will permeate research in SWCNTs for the next few years: chemistry, chirality, and complexity. The quality of commercially available SWCNT samples, coupled with advances in characterization techniques, particularly microscopy, facilitates complex chemical derivatization of SWCNTs with reliable structural characterization. The endohedral modification of SWCNTs, inclusion of quantum defects, and synthesis of mechanically interlocked derivatives are illustrative examples. We also overview how enantiomeric resolution of SWCNTs enables new fields of research such as chiral sensing, catalysis, and spin filtering. Complexity, once seen as an enemy, now shows promise in several fields, as exemplified by physically unclonable functions and neuromorphic computing. These three axes, controlled chemical modification, chiral discrimination, and system-level complexity, are increasingly interwoven, defining an emerging research landscape for SWCNTs. Taken together, they offer a framework for reimagining the roles of SWCNTs in both fundamental science and technology. We hope this review inspires innovative research lines and encourages young scientists to focus on SWCNTs.

pubs.acs.org

"Los modelos de lenguaje no planifican; generan textos que parecen planes. Los modelos de lenguaje no resuelven problemas; generan textos que parecen soluciones. Los modelos de lenguaje no piensan; generan textos que parecen como si lo hicieran." Andriy Burkov

🔊 Just out in @jacs.acspublications.org! The results of a fruitful collaboration with the group of L. Sangaletti at Università Cattolica del Sacro Cuore. MINTs sniff out VOCs 👃 pubs.acs.org/doi/full/10.... 1/3

Efficient Implementation of MINT-Based Chemiresistor Arrays for Artificial Olfaction

We demonstrate the possibility of using an array of MINT-based chemiresistors for the selective detection of VOCs at room temperature. Four new types of MINTs with different functional groups (MINTALKENE (X:–CH = CH2), MINTCOOMe (X:–COOMe), MINTCOOH (X:–COOH), and MINTOH (X:–CH2OH)) were specifically synthesized to prepare a set of six sensing layers, which included, in addition to the new MINTs, a pristine SWNTs layer and a MINTXYLENE layer. The functionalized sensing layers were tested by exposing them to NH3, NO2, EtOH, IPA, acetone, benzene, and NaClO vapors in the ppm range. We showed that MINT functionalization enhances response to analytes with respect to pristine SWNTs. When assembled into an array, our sensing layers can operate at room temperature as an electronic nose, disclosing the possibility of using these layers in low-power-consumption wearable devices. Correlation plots, PCA, and UMAP analysis show that a remarkable discrimination of ammonia with respect to interfering gases can be reached by the e-nose. Gas mixtures were also discriminated, as shown for NH3/ethanol, acetone/ethanol, and isopropanol/acetone mixtures, which are relevant in view of breathomics applications. The efficient preparation method of sensing layers allows for an improvement of performance, as shown for one of the best performing chemiresistors in the set, resulting in a sensitivity increase (up to 10×) and a dramatic reduction of response and recovery times.

pubs.acs.org

Hey @ISMSC2025 attendees, have you met Louis? If you want to hear about helical foldamers that form homo- and heteroduplexes through complementary interactions, go talk to him! :-) By the way, Louis will defend his PhD dissertation at the end of October... just saying!

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🔥 Our latest research on ultrashort carbon nanotubes (uCCNTs) with luminescent color centers has been published in ACS Nano! We've discovered that these uCCNTs are exceptionally bright in the NIRII window, making them ideal for advanced bioimaging, photonics, and quantum science applications.

Ultrashort Carbon Nanotubes with Luminescent Color Centers Are Bright NIR-II Nanoemitters

In the fields of bioimaging, photonics, and quantum science, it is equally crucial to combine high brightness with a nanoscale size in short-wave infrared (SWIR) emitters. However, such nanoemitters a...

pubs.acs.org