Check out our just published work in Advanced Science with @isra-group.bsky.social on a novel concept about The Preparatory (Anti)Bonding Character of Molecular Orbitals. Congrats to the main player in this fascinating journey @jonasoliverwenzel.bsky.social t.co/GoOgKALx0P …

Are you interested in radical #chemistry or redox-active ligands? New work by @brehergroup.bsky.social about the isolation of a stable radical dianion is now in early view @helvchimacta.bsky.social as part of a special issue dedicated to Prof. Dr. Armido Studer. #chemsky doi.org/10.1002/hlca...

Isolation of a Monomeric Bis(pyridylimino) Isoindolide (BPI) Radical Dianion and Further Insights Into Structures of Reduced BPI Compounds

This article reports on the isolation of a monomeric compound with a dianionic singly reduced bis(pyridylimino) isoindolide (BPI) ligand and elaborated discussions on the structure of reduced BPIs.

doi.org

New paper now out in Early View @angewandtechemie.bsky.social ! We @brehergroup.bsky.social describe radical #photochemistry of main group #organometallics with visible light. With our article we want to make the described concept accessible to a broader #chemistry community. #Chemsky

Very nice group excursion of the Hinz and Breher lab today! Many thanks to all involved 👍👍👍

Had a wonderful time at #EuCOMC 2025 in Bern! Thank you @evaheviagroup.bsky.social and @albrecht-lab.bsky.social for organizing a really great conference!

Felix Krämer@felixkraemer.bsky.social · last yr.

Met some friends at the beautiful #EuCOMC conference in beautiful Bern. @jonasoliverwenzel.bsky.social @pascalweisenb.bsky.social

Are you interested in Main Group Photochemistry? Check out our recent Review about E-C bond photolysis 👇

Breher Research Group@brehergroup.bsky.social · last yr.

Excellent review by @jonasoliverwenzel.bsky.social and Johannes Werner on "Non-Innocent Ligands as Mediators for Visible-Light-Initiated Element–Carbon Bond Homolysis in Main Group Chemistry" just out in @angewandtechemie.bsky.social 👍👉 doi.org/10.1002/anie...

#TopViewedArticle 👍 We are delighted to share that our work, published in EurJIC @wiley.com, has ranked within the top 10% of most-viewed papers published by the journal in 2023 👉 doi.org/10.1002/ejic...

Synthesis and Characterization of Bis(pyridylimino)isoindolide Alkali Metal Complexes in Three Redox States

This work reports on the synthesis and characterization of alkali metal complexes of BPI and Me2BPI in reduced oxidation states. CV, EPR and XRD studies revealed detailed information about the unknow...

doi.org

The first mono ortho-phenylene bridged Al/P FLP was synthesized and characterized. Its reactivity was probed against several small molecules. Thanks to Melina Dianas 👍 doi.org/10.1002/ejic...

Reactivity of an ortho‐Phenylene‐bridged Al/P Frustrated Lewis Pair Towards Small Molecules

Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho-phenylene bridge...

doi.org

A detailed study on the reactivity of ambiphilic metallacycles is presented. Thanks to @felixkraemer.bsky.social, @pascalweisenb.bsky.social and @isra-group.bsky.social)! Have a look at the paper 👉 doi.org/10.1002/ejic...

Stabilities and Limitations in the Reactivity of Phosphorus Ylide‐Based Aluminum‐ and Gallium‐Carbon Ambiphiles − A Combined Experimental and Computational Approach

The unexpected reactivity and stability limits of phosphorus ylide-based aluminum- and gallium-carbon ambiphiles are described. While the previously published t-butyl-substituted compound (2-{AltBu2}...

doi.org

Many thanks to @joshabbenseth.bsky.social and Frank Tambornino for highlighting our collaborative study on the organometallic and photochemistry of R2Al(BPI) complexes in „Trendbericht Anorganische Chemie 2025“ 👍👍👍 onlinelibrary.wiley.com/doi/10.1002/...

Let’s start here with our last post from the other timeline: Many thanks to the Podlech group for letting us be part of this nice study: A Stable Carbon‐Centered Radical Showing Six Amphoteric Redox States. Now out in Chem Eur J. chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...

A Stable Carbon‐Centered Radical Showing Six Amphoteric Redox States

A fully conjugated system built by alternate fusion of four benzene and three cyclopentadiene rings is a further rare example of an air- and moisture-stable carbon-centered hydrocarbon radical. It wa...

chemistry-europe.onlinelibrary.wiley.com