Maksym Kovalenko

@maksymuki.bsky.social

Professor at ETH Zurich and Empa

Tin halide perovskite nanocrystals will have a bright future—with bright emission! ✨ ❌ Stop attributing 2D-impurity PL to the NCs ❌ Eliminate 2D impurities via amine-free synthesis. ✅ Start de-doping to manage intrinsic p-doping. ​https://advanced.onlinelibrary.wiley.com/doi/10.1002/adma.202523678

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Electrochemical Control over Electron Density of InAs Quantum Dots

Control over the electron density and conductivity is a cornerstone of semiconductor technology. Here, we report electrochemical control over electron density and conductivity in films of InAs colloidal quantum dots (QDs) capped with ethanedithiol ligands. The quantum-confined twofold degenerate 1S1/2(e) electron state can be reversibly and completely filled. Increasing the electron population yields four bleach features in the optical-absorption spectrum associated transitions to the 1S1/2(e) state, and state-resolved electronic conductivity which follows the 1S1/2(e) density of states, reaching a maximum of 0.45 S/m at 0.5 electrons per QD. The absence of 1P(e) bleach features and state-resolved conductivity imply a wide separation between the 1S1/2(e) and 1P(e) states resulting in electronic transport between 1S(e) states exclusively. The reversible electrochemistry of InAs QDs films allows determination of the absolute energy levels. InAs QDs of 4.2 nm in edge length and capped with ethanedithiol ligands are natively n-doped with the Fermi level at −4.6 eV, the 1S1/2(e) state at −4.28 eV and the 1S3/2(h) state at −5.54 eV vs vacuum. This work establishes a way to precisely control the charge carrier density and conductivity and gives insights into the charge transport properties and electronic structure of InAs QD films, opening the possibility of making devices with InAs QDs in which the charge carrier density is precisely controlled electrochemically.

pubs.acs.org

This monumental effort, undertaken by many outstanding co-authors, including several invited speakers from the Nanax 2023 conference, which we co-organized, is now online. Special kudos to Maria Ibáñez and her team. pubs.acs.org/doi/10.1021/...

Prospects of Nanoscience with Nanocrystals: 2025 Edition

Nanocrystals (NCs) of various compositions have made important contributions to science and technology, with their impact recognized by the 2023 Nobel Prize in Chemistry for the discovery and synthesis of semiconductor quantum dots (QDs). Over four decades of research into NCs has led to numerous advancements in diverse fields, such as optoelectronics, catalysis, energy, medicine, and recently, quantum information and computing. The last 10 years since the predecessor perspective “Prospect of Nanoscience with Nanocrystals” was published in ACS Nano have seen NC research continuously evolve, yielding critical advances in fundamental understanding and practical applications. Mechanistic insights into NC formation have translated into precision control over NC size, shape, and composition. Emerging synthesis techniques have broadened the landscape of compounds obtainable in colloidal NC form. Sophistication in surface chemistry, jointly bolstered by theoretical models and experimental findings, has facilitated refined control over NC properties and represents a trusted gateway to enhanced NC stability and processability. The assembly of NCs into superlattices, along with two-dimensional (2D) photolithography and three-dimensional (3D) printing, has expanded their utility in creating materials with tailored properties. Applications of NCs are also flourishing, consolidating progress in fields targeted early on, such as optoelectronics and catalysis, and extending into areas ranging from quantum technology to phase-change memories. In this perspective, we review the extensive progress in research on NCs over the past decade and highlight key areas where future research may bring further breakthroughs.

pubs.acs.org

Another paper form our team, advancing novel quantum light sources. Single Perovksite QDs can produce not only single photons on demand, but also degenerate photon pairs. pubs.acs.org/doi/10.1021/...

Energy-Degenerate Photon-Pair Generation from Individual CsPbBr3 Quantum Dots

Beyond single-photon emission, generating correlated N-photon bundles, e.g., a photon pair, is essential for various quantum technologies including quantum teleportation and metrology. A widely explored approach exploits the radiative biexciton cascade in individual (mainly epitaxially grown) quantum dots (QDs). Here, we investigate such a cascade in colloidal CsPbBr3 QDs, a scalable and solution-processable quantum-light emitter. By matching their size-dependent biexciton binding energies to their size-independent phonon energies, we demonstrate the generation of time-correlated and energy-degenerate photon pairs in large (>15 nm) QDs. Under pulsed excitation at 4 K, we observe pronounced photon bunching, with a g(2)(0) of up to 7 in Hanbury Brown and Twiss measurements. The excitation-density-dependent bunching is quantitatively reproduced by multicolor numerical calculations, suggesting the cascade involving biexciton and phonon-mediated exciton decay as origin of the photon pair. Our findings provide new insights into energy-degenerate photon-pair generation in these highly engineerable quantum-light emitters, marking important steps toward their application in quantum-information technologies.

pubs.acs.org