Nanochemistry Lab

@nanochemistrylab.bsky.social

Nanochemistry Lab | Paolo Samorì | @unistra.fr | @cnrs.fr 👩‍🔬👨‍🔬🇮🇹🇵🇱🇫🇷🇪🇸🇨🇳🇱🇧🇵🇰🇪🇬🇸🇦🇹🇭 in 🇫🇷 Strasbourg, France https://nanochemistry.isis.unistra.fr/

🎓 Prof. Paolo Samorì has been awarded the ECIS-Syensqo Award 2026! 🧪 This prestigious distinction recognises his pioneering research at the crossroads of chemistry, materials science, and nanotechnology, and his major impact on colloid and interface science

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🌱 Turning greenhouse gas into green fuel just got a whole lot slicker! Our new “waterproof” catalyst shield repels excess moisture, enabling efficient CO₂-to-methane conversion even in strong acids. A major step towards stable, clean energy tech ♻️ 🔗 doi.org/10.1093/nsr/...

Molecularly engineered covalent hydrophobic interface for enhanced CO2 electromethanation in strong acid

This study develops a molecularly engineered covalent hydrophobic interface that enables highly efficient electrocatalytic reduction of CO2 to methane unde

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🏋️ Under pressure? So are next-gen wearables! Our new review explores how flexible pressure sensors help devices “feel” the world around them, powering everything from health monitoring and e-skin to soft robots and smarter human–machine interactions 🦾 🔗 doi.org/10.1002/adfm...

Design Strategies and Emerging Applications of High‐Performance Flexible Piezoresistive Pressure Sensors

Flexible piezoresistive pressure sensors underpin wearable and soft electronics. This review links sensing physics, including contact resistance modulation, quantum tunneling and percolation, to unif...

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✂️ One atom changes everything! We edited gold-copper nanoclusters atom-by-atom and flipped their glow mechanism inside-out, unlocking a new way to engineer light for solar cells and printed electronics ⚡ Read the full open-access paper here 👇 doi.org/10.1002/smll...

Manipulating the Photoluminescence Pathway in Metal Nanoclusters by Atomic Structural Editing

The manipulation of the photoluminescence pathways in metal nanoclusters through atomic-scale structural editing represents a major scientific challenge. Here, Au18Cu5(SAdm)15 and Au17Cu4(SAdm)15 nan...

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🧵 Big news for smart textiles! By confining PEDOT:PSS polymers within COF nanopores, we suppressed water-induced swelling and degradation. The result? Ultra-strong, durable conductive fibers that retain >90% performance for wearable electronics! 🩺👕 👉 doi.org/10.1021/acsa...

Confinement of PEDOT:PSS in Covalent Organic Frameworks for Stable Organic Electrochemical Transistors

Organic electrochemical transistors (OECTs) are attractive for wearable bioelectronics and smart textiles owing to their mixed ionic-electronic conduction and biocompatibility. The function of these t...

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☀️ A “solar harvester” based on a 2D BODIPY framework turns sunlight and air into hydrogen peroxide – clean, simple, no messy steps ♻️ The future of light-powered fuels starts here! ⚡ Read more 👉 doi.org/10.1021/acs.... 🤝🇨🇳🇫🇷 #cas #zju @unistra.fr @cnrs.fr @cnrs-alsace.bsky.social

BODIPY-Driven π-Extended Frameworks for Efficient Photosynthesis of Hydrogen Peroxide

Hydrogen peroxide (H2O2) is an indispensable industrial feedstock and energy carrier, yet its synthesis is challenging due to the energy-intensive property and complex postpurification process. Direct photocatalytic H2O2 production from water and air offers a promising approach to addressing these problems, while obtaining efficient and robust photocatalysts has been a longstanding challenge. Herein, we describe the design and synthesis of a two-dimensional conjugated BODIPY-based framework (2D CBF) via BODIPY-mediated topologic aldol-type polycondensation. The strong solar-harvesting BODIPY units and 2D extended conjugation endow the 2D CBF with near-infrared absorption and abundant oxygen adsorption sites. Consequently, the resulting 2D CBF demonstrates a remarkable H2O2 production rate up to ∼56.8 mmol h–1 gcat–1 and benchmark apparent quantum yield of 21.9% without cocatalyst and sacrificial agents, largely superior to the BODIPY molecule. In a large-scale paradigm, the 2D CBF-based floatable photocatalysis platform (∼0.2 m2) could efficiently uptake reactant (O2) from air and produce H2O2 at a rate up to ∼15 mmol h–1 m–2 under sunlight irradiation. This work highlights the two-dimensional strategy and BODIPY building blocks for designing and synthesizing highly efficient photocatalytic platforms.

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🧊 “Frozen” graphene? By using rapid heat quenching during reduction of graphene oxide, we’ve created a 2D amorphous carbon that’s liquid-processed and scalable, revealing a “universal” secret to how electricity flows through disordered materials! ⚡️ 🔗 doi.org/10.1002/smll...

Liquid‐Processed 2D Aromatic Amorphous Carbon: Defect Engineering and Universal Transport Scaling

Liquid-processed graphene oxide (GO) thin films undergo a controllable crystalline–to–amorphous transition driven by thermal quenching. By kinetically tuning oxygen-driven defect formation during red...

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💡 Light-controlled ultrathin electronics are here! We engineered 2D organic crystals that precisely tune current with light, enabling stable 6-bit memory in a single molecular layer. A big step towards high-density, programmable optoelectronics! ⚡️ 🔗 doi.org/10.1021/jacs...

Precise Optical Modulation of Charge Transport in 2D Organic Molecular Crystals through Tailor-Designed Photoswitchable Guest–Host Architectures

Two-dimensional organic molecular crystals (2DOMCs) have emerged as promising candidates for next-generation ultrathin electronics. However, precisely and reversibly modulating their charge-transport characteristics remains a significant challenge. Herein, we report a molecular engineering strategy to create light-programmable field-effect transistors (FETs) based on a monolayer thick 2DOMCs, which is achieved by dispersing photochromic diarylethene (DAE) guests into a crystal host matrix of 2,6-bis(4-hexylphenyl) anthracene (C6-DPA). By systematically functionalizing the DAE periphery with substituents of varying electron-donating and -withdrawing strengths, we precisely tune the HOMO energy levels of the guest molecules. We identify DAE-OCH3 as the optimal dopant, which enables a 54% modulation of the FET current within just 5 s of UV light “writing” process. Notably, the optimized C6-DPA/DAE-OCH3 (15%) guest–host system exhibits approximately 85 distinct and stable current levels, corresponding to a storage capacity exceeding 6 bits, with excellent retention over 16 days. This performance represents a significant advancement in ultrathin multilevel memories based on high-mobility organic semiconductors. Our approach establishes a general platform for developing stimuli-responsive 2D organic materials with programmable (opto)electronic properties, opening new avenues for high-density data storage and future generation intelligent (opto)electronics.

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🌡️ Cooling and heating single Ti₃C₂Tₓ MXene flakes tunes their disorder – and with it, their electronic and magnetotransport properties. From quantum effects at low temperatures to a metal → disordered-metal transition, temperature is the key! ⚡️ 🔗 doi.org/10.1021/acsa...

Influence of Disorder on the Electronic Properties and Magnetotransport of Ti3C2Tx Single-Flake Devices

The exploration of MXenes for electronic applications is a rapidly growing field in materials science. However, most research has focused on MXene films, with only a limited number of studies addressi...

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