whitney loo

@whitneysloo.bsky.social

assistant professor chemical engineering UW-Madison | all things polymers & electronic music | she/her 🌈

Our latest publication is out now! Led by Jenny, we study charged-neutral polymer blends and show that divalent ion identity strongly influences the nanostructure. we even report microphase separation at lengthscales typically observed in block copolymers! Read it here: pubs.acs.org/doi/10.1021/...

Tunable Nanoscale Structure via Divalent Ion Identity in Charged-Neutral Polymer Blends

Charged-neutral polymer blends, wherein an ion-containing polymer is blended with a neutral polymer, are potential candidates for battery electrolytes due to their improved ion transport properties and electrochemical stability. Though electrostatic interactions in charged polymer blends can theoretically stabilize ordered nanostructures analogous to those observed in neutral block copolymers, direct experimental evidence remains limited. Here, we investigate the effects of divalent cation identity on the nanoscale morphology of charged-neutral polymer blends composed of poly(ethylene oxide) (PEO) and Mg2+ or Ca2+ ion-containing polymers, poly[3-(methylacryloxy)propylsulfonyl-1-(trifluoromethanesulfonylimide)] (P(Mg(MTFSI)2) or P(Ca(MTFSI)2). By tuning the size of the divalent counterion, we are able to precisely tune the ion solvation between the free cation and PEO, which acts as a solvent in this system. Differential scanning calorimetry (DSC) and small-angle X-ray scattering (SAXS) measurements reveal that Mg2+ and Ca2+ ions induce distinct structural behavior. In both systems, the blends become more miscible as the concentration of ion-containing polymer is increased indicated by increased suppression of PEO crystallinity. At the highest concentrations of P(Mg(MTFSI)2), the blends undergo microphase separation and generate nanostructures with short-ranged ordering. In contrast, calcium ions, which are more readily solvated by PEO, produce more homogeneous blends characterized by a single glass-transition temperature and featureless SAXS data. The results demonstrate the novel experimental confirmation that charged-neutral polymer blends can undergo microphase separation and show that counterion identity can be exploited as a design parameter to control nanoscale morphology.

pubs.acs.org

the second Loo Lab paper is out! here we use a combined SAXS/SANS approach to study the phase behavior of charged-neutral polymer blends. despite being macroscopically miscible, these blends form disordered nanostructures due to ionic interactions pubs.acs.org/doi/full/10....

The Influence of Charge Correlation and Ion Solvation on the Phase Behavior of Single-Ion Conducting Polymer Blend Electrolytes Using SAXS/SANS

Single-ion conducting polymer blends (SICPBs) have demonstrated exceptional electrochemical performance as solid-state battery electrolytes; however, their nanoscale morphology and thermodynamic behavior remain unexplored. In this work, we investigate blends composed of deuterated poly(ethylene oxide) and poly[lithium sulfonyl(trifluoromethane sulfonyl)imide methacrylate], dPEO/P(LiMTFSI), and report the first experimental study of the nanostructures of charge-neutral polymer blends using small-angle neutron scattering (SANS) and small-angle X-ray scattering (SAXS). Despite the macroscopic miscibility indicated by a single glass-transition temperature, SANS and SAXS results reveal disordered, charge-correlated nanostructures that are strongly influenced by blend composition and temperature. At low concentrations of charge polymer, the scattering is dominated by concentration fluctuations, and the random phase approximation is applied to extract values of the Flory–Huggins interaction parameter, χSC. At higher charged polymer content, concentration fluctuations are suppressed, and a correlation model is used to characterize the nanostructures of the charge correlations. We find that the structures of the charge correlations are highly dependent on blend composition─consistent with predictions from Sing’s self-consistent field theory-liquid state models. Understanding these features is essential for uncovering the ion transport mechanism that leads to improved electrochemical performance previously reported in SICPB systems.

pubs.acs.org

If you're a UCLA researcher (PI, grad student, etc) with an NSF, NIH or other suddenly suspended grant, please email or DM me. I'm trying to confirm what the suspension letters say and how extensive the NIH suspensions are. Email: Mikhail at calmatters dot org

Mikhail Zinshteyn@mzinshteyn.bsky.social ¡ last yr.

I chased this all day: UCLA research grants suspended after Trump administration faulted campus for antisemitism calmatters.org/education/hi...

my group is looking to hire a postdoc to work on a variety of polymer-related projects of their choosing! If you know of any outstanding candidates that are looking for postdoctoral positions, please send them my way

do you ever stare at the ceiling and think about how the worldwide scientific establishment did the impossible and created a COVID vaccine in under a year and the response of the general public has been to go on an unstoppable rampage to destroy science and scientists

Baldwin to RFK Jr: "Is funding for Alzheimer's research centers DEI? Because you're holding up $65m for 14 of those centers in 9 states, including UW Madison. Is funding for cancer centers DEI? Because you're holding up $47m in cancer center support grants at 9 cancer centers in 8 states."

A 50% cut to science funding (which is close to what Trump is proposing for NIH) would result in huge negative long-term economic outcomes: *7.6% cut in GDP *8.6% cut in federal revenues *equivalents of making the average American $10,000 poorer

Alondra Nelson@alondra.bsky.social ¡ last yr.

"If you look at a long period of time, a lot of our increase in living standards seems to be coming from public investment in scientific research." The devastating cuts to science funding aren't just academic, they threaten our livelihoods and wellbeing. www.nytimes.com/2025/04/30/b...

I created and taught a machine learning course for chemical engineers this semester. In my last lecture I cover ethical issues and I told a story about the connection between chemical physics, large language models, and copyright law. Read on if you want to know more!

Harvard will not comply. “No government — regardless of which party is in power — should dictate what private universities can teach, whom they can admit and hire, and which areas of study and inquiry they can pursue.” — Harvard President Alan M. Garber www.thecrimson.com/article/2025...

Harvard Will Fight Trump’s Demands | News | The Harvard Crimson

Harvard will not comply with the Trump administration’s demands to dismantle its diversity programming and limit student protests in exchange for its federal funding, University President Alan M. Garb...

thecrimson.com

SCAM ALERT. This is a fake conference that ripped off my and other people’s names to trick people into registering. There is no such conference that I or the others shown were invited or agreed to. We are working to try to get this fraud taken down from the web. chemsymposia.com

Join Chemsymposia 2026: Research & Innovation | ChemSymposia 2026

Join us at Chemsymposia 2026 to discover groundbreaking research in physics applications. Connect with experts, engage in insightful discussions, and explore our venue, registration details, and speak...

chemsymposia.com

If you don't want to see this horrible garbage happen in every future high-stakes election, make sure it demonstrably fails in the Wisconsin Supreme Court race by helping elect Susan Crawford

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