Michael Hurst

@chemhurst.bsky.social

Managing Editor at the American Chemical Society, Washington DC | Chemistry PhD 2022 from University of Oregon | views (when seldom expressed) are my own

Read the newest Pioneers & Influencers article on Prof. Bob Morris in Organometallics! pubs.acs.org/doi/10.1021/...

Demyan 🇺🇦 Prokopchuk ⌬@dpro.bsky.social · 10mo ago

It has been an honour and privilege to co-write this piece in honour of Bob! pubs.acs.org/doi/10.1021/ac… (Want to know how many papers Bob has in his self-curated digital reference library that he started in 1989? The answer will surprise you! Read the article to find out 😉)

Today is the day! Tune in as four incredible researchers from the US and Canada discuss their work on AI and Machine Learning in Chemistry, with each presentation followed by live Q&A. Register: rsc.zoom.us/webinar/regi... #chemsky

Michael Hurst@chemhurst.bsky.social · last yr.

Join us April 14 for the RSC Americas Emerging Investigators webinar on AI/ML in Chemistry! Featuring talks from Jolene Reid (UBC), César de la Fuente (UPenn) @delafuentelab.bsky.social, Adji Bousso Dieng (Princeton) @adjiboussodieng.bsky.social, and Connor Coley (MIT) rsc.zoom.us/webinar/regi...

Poster promoting an event from the Royal Society of Chemistry, "RSC Desktop Seminar: Americas Emerging Investigators - AI and Machine Learning II" on Monday 14 April 2025, 12pm EST or 5pm UK time

RSC Americas is hiring! Applications are accepted until 18 March for the Content Development Editor role based in Washington DC. This is an excellent opportunity to join an internationally renowned science organization on a great team supporting research and researchers in North America #chemsky

Royal Society of Chemistry hiring Content Development Editor in Washington, DC | LinkedIn

Posted 1:18:17 AM. Join the Royal Society of Chemistry's North American team as a Content Development Editor and…See this and similar jobs on LinkedIn.

linkedin.com

Shortly after, we published this less sprawling follow up article with our developed system. I really enjoyed this paper - published Editors Choice in Organometallics after acceptance with no revisions!! pubs.acs.org/doi/abs/10.1...

The Influence of Silane Steric Bulk on the Formation and Dynamic Behavior of Silyl Palladium Hydrides

Silanes play a versatile role in catalytic transformations, acting as hydride sources, transmetalation reagents, and starting materials in the synthesis of highly valued organosilicon compounds and polymers. Their use in catalysis with palladium is widespread, commonly proposed to proceed via oxidative addition of Si–H to Pd(0); however, little is known about this fundamental reaction. Here, we show that the formation of silyl palladium hydride complexes (dcpe)PdH(SiR3), which exist in equilibrium with starting materials [(μ-dcpe)Pd]2 (dcpe = dicyclohexyl(phosphino)ethane) and tertiary silanes HSiR3 in solution, is dependent on the steric profile of the silanes employed. A lower Keq is observed with increasing steric encumbrance at silicon, correlating well with each substituent’s Charton value, and van’t Hoff analyses show the reaction with sterically congested silanes to be less thermodynamically favorable. Variable temperature kinetics studies likewise reveal a preference for unhindered silanes as determined by Charton and Eyring analyses. On the other hand, the intramolecular ligand exchange of H/SiR3 on the formed complexes is unaffected by silane steric bulk. Together, the energetic parameters derived for each of these steps reveal that thermodynamic factors are primarily responsible for favoring (silyl)Pd(H) formation with less sterically bulky silanes. These results present the first systematic study on the role of silane steric effects in oxidative addition of Si–H to Pd(0) and help to inform organosilicon chemistry with late transition metals.

pubs.acs.org

Using the transition to Bluesky (and its incorporation into AltMetric scores) as an excuse to shamelessly self promote some work I did at Oregon. I put years and years into this project while helping start up the Amanda Cook Lab - read this beast of a paper in Chem Sci pubs.rsc.org/en/content/a...

The mechanism of oxidative addition of Pd(0) to Si–H bonds: electronic effects, reaction mechanism, and hydrosilylation

The oxidative addition of Pd to Si–H bonds is a crucial step in a variety of catalytic applications, and many aspects of this reaction are poorly understood. One important yet underexplored aspect is ...

pubs.rsc.org