Pleased to share Falk’s latest work @ghadwalgroup.bsky.social on a non-classical germanium diradicaloid, just published in @angewandtechemie.bsky.social highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/10.1002/... thanks to @dfg.de

Bicyclo[1.1.0]tetragermane‐2,4‐diide Diradicaloid

The bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid compound [(ADC)2Ge4] featuring a stretched bridgehead Ge─Ge bond is reported as a Venetian red crystalline solid. [(ADC)2Ge4] has been characteri...

onlinelibrary.wiley.com

Reversible single-electron-transfer (SET) in #maingroup systems—cyclic pnictogen radicals—analogs of aryl radical anions in Birch reductions— @angewandtechemie.bsky.social Congratulations to Henric and all @ghadwalgroup.bsky.social @basdebruin.bsky.social onlinelibrary.wiley.com/doi/10.1002/...

Delighted to share the first original research article of 2025 by @ghadwalgroup.bsky.social ... in @angewandtechemie.bsky.social dedicated to @remglasgow.bsky.social thanks to @dfg.de 👉 Lithium Anionic Dicarbenes or Acetylides: What is in the Name? onlinelibrary.wiley.com/doi/10.1002/...

Very happy to share that our research @ghadwalgroup.bsky.social on 1,4-Disilabenzenes @acsjacs.bsky.social has been highlighted in #synfacts: www.thieme-connect.com/products/ejo...

1,4-Disilabenzenes: Low-Valent Silicon Aromaticity

Thieme E-Books & E-Journals

thieme-connect.com

Excited to share this fantastic collaboration with Ghadwal_Group just published in JACS @acspublications.bsky.social on Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids pubs.acs.org/doi/10.1021/...

Structural Snapshots of Reversible Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids

Although diradicals should exhibit a rather small reaction barrier as compared to closed-shell species for activating kinetically inert molecules, the activation and functionalization of carbon dioxid...

pubs.acs.org