Pleased to share Falk’s latest work @ghadwalgroup.bsky.social on a non-classical germanium diradicaloid, just published in @angewandtechemie.bsky.social highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/10.1002/... thanks to @dfg.de

Bicyclo[1.1.0]tetragermane‐2,4‐diide Diradicaloid

The bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid compound [(ADC)2Ge4] featuring a stretched bridgehead Ge─Ge bond is reported as a Venetian red crystalline solid. [(ADC)2Ge4] has been characteri...

onlinelibrary.wiley.com

The Hudnall lab is hiring a Postdoctoral Fellow! Applicants excited about joining our recently relocated research group and interested in the synthesis of exotic main-group molecules, materials and heterodiatomics can email Dr. Hudnall directly. Please share!

Check out our work just accepted in @chemistryeurope.bsky.social (ChemEurJ) on Understanding Small Molecule Activation by Heavier Benzene 1,4‐diides: Interplay between Diradical Character and Aromaticity @ghadwalgroup.bsky.social chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...

Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4‐diides: Interplay between Diradical Character and Aromaticity

The intricate relationship between diradical character, aromaticity, and reactivity in annulated heavier Group 14 benzene-1,4-diides, i.e. [(ADC)E]2 (E = Si, Ge, Sn), based on an anionic dicarbene fr...

chemistry-europe.onlinelibrary.wiley.com

Reversible single-electron-transfer (SET) in #maingroup systems—cyclic pnictogen radicals—analogs of aryl radical anions in Birch reductions— @angewandtechemie.bsky.social Congratulations to Henric and all @ghadwalgroup.bsky.social @basdebruin.bsky.social onlinelibrary.wiley.com/doi/10.1002/...

Paneth’s mirrors and the isolation of methyl radicals www.chemistryworld.com/opinion/pane...

Paneth’s mirrors and the isolation of methyl radicals

Laying the groundwork for the study of combustion and photochemical reactions

chemistryworld.com

Delighted to share the first original research article of 2025 by @ghadwalgroup.bsky.social ... in @angewandtechemie.bsky.social dedicated to @remglasgow.bsky.social thanks to @dfg.de 👉 Lithium Anionic Dicarbenes or Acetylides: What is in the Name? onlinelibrary.wiley.com/doi/10.1002/...

Very happy to share that our research @ghadwalgroup.bsky.social on 1,4-Disilabenzenes @acsjacs.bsky.social has been highlighted in #synfacts: www.thieme-connect.com/products/ejo...

1,4-Disilabenzenes: Low-Valent Silicon Aromaticity

Thieme E-Books & E-Journals

thieme-connect.com

Excited to share this fantastic collaboration with Ghadwal_Group just published in JACS @acspublications.bsky.social on Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids pubs.acs.org/doi/10.1021/...

Structural Snapshots of Reversible Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids

Although diradicals should exhibit a rather small reaction barrier as compared to closed-shell species for activating kinetically inert molecules, the activation and functionalization of carbon dioxid...

pubs.acs.org

Hi All, We (Ghadwal Research Group at Uni Bielefeld) are now on @bsky.app and wish you all the best for 2025. 🕊️🫶🌍👐