Matilde Concilio

@matildeconcilio.bsky.social

🧬Polymer chemist deeply interested in soft matter and biomaterials 🧪Research associate in antimicrobial materials and biomimetic, Contini group, Imperial College London ⚗️Former postdoc research fellow, Williams group, University of Oxford

Just like that, #APME2025 has come to an end! It was a real pleasure to present my research on dynamic networks♻️ I’m always amazed by the number of new connections made at events like this—outstanding science in an outstanding location 🌋Hope to see you all again in Canada in two years!

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Thrilled to share this work on precise COOH-functionalized polyesters in reprocessable vitrimers, now online in JACS! This research highlights the role of catalysts in vitrimer chemistry and how tailored catalyst mixtures can control vitrimer properties and bond exchange pubs.acs.org/doi/10.1021/...

Precise Carboxylic Acid-Functionalized Polyesters in Reprocessable Vitrimers

Thermosets are valued for their exceptional dimensional stability, mechanical properties, and resistance to creep and chemicals. Their permanent molecular structures limit reshaping, reprocessing, and recycling. Incorporating exchangeable chemical bonds into cross-linked polymer networks provides materials with thermoset-like properties that are also reprocessable. Here, ring-opening copolymerization (ROCOP) of unpurified, commercially available epoxides and succinic anhydride is employed to synthesize well-defined, low molecular weight polyesters with controlled functionalization. Polymer networks are then formed through the catalyzed reaction of these copolymers with the epoxy-containing cross-linker diglycidyl ether of bisphenol A. Catalyst mixtures of zinc bis(2-ethylhexanoate) and 1,8-diazabicyclo(5.4.0)undec-7-ene are used to assess the role of the catalysts in the curing and dynamic bond exchange reactions. Varying the catalyst ratios results in polymer networks with tunable mechanical properties (90% < εb < 450%, 0.30 MPa < UTS < 24 MPa), high creep recovery (%recovery > 90% after five creep cycles), and good reprocessability.

pubs.acs.org

Last week I had the opportunity to visit Scott Bader and test some of my materials. It was an incredibly instructive experience. Learning how to prepare and test samples for industrial applications gave me valuable insights to optimise my work. I also fabricated my first composite—a proud moment! 👩🏻‍🔬🧪

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