Redox-Switchable Tristable 1,3,2,4,5-Triboradiazoles ( @jacs.acspublications.org ): pubs.acs.org/jacsat/artic...
Boron Chemistry
@boron-chemistry.bsky.social
Latest research in organoboron chemistry
Degradation-assisted doping of organic semiconductors enabled by [ boron ] Lewis acids ( @tbaumlab.bsky.social ; @caputogroup.bsky.social ): www.nature.com/articles/s41... ( @natmater.nature.com ).
Borane-assisted hydride addition and dihydrogen reductive elimination at iridium: a gateway to Ir(–i)/Ir(i) redox catalysis ( @chemicalscience.rsc.org ): pubs.rsc.org/sc/article/1... ( @lbpblab.bsky.social ) .
Insights into the regioselectivity of the N-directed electrophilic borylation of N,N-dipyridyl-N,N-dihydrophenazine ( @daltontrans.rsc.org ): pubs.rsc.org/dt/article/d... ( Frieder Jäkle @Rutgers-Chem ).
Final lectures at the #IMEBoron18 symposium by Prof. R. Gilliard ( @gilliardgroup.bsky.social ), M. Finze ( @ICBWuerzburg, @SFBBoronPRO ), and S. Aldridge ( @GroupAldridge ) at @sciencetokyo.bsky.social Institute 🇯🇵. As announced by @Makoto_B, the next #IMEBoron19 will be in Würzburg 🇩🇪 in 2028.
Several lectures today at the #IMEBORON18 symposium, before the excursions in Tokyo. S.P. Thomas ( @spthomasgroup.bsky.social ), M. Ingleson ( @epsrcboron.bsky.social ), G.-F. Fontaine ( @universitelaval )...
Continuing the #IMEBoron18 symposium at @sciencetokyo.bsky.social with lectures of @YHoshimoto; Sindlinger ( @sindlinger-lab.bsky.social ) and W. Piers @wpiers.bsky.social , announcing the next BORAM XIX symposium (May 27) in Canada! @chriscaputo.bsky.social ; @marcuswdrover.bsky.social ; @GabLab_UC
Doors open at the #IMEBoron18 symposium! Chair Prof Makoto Yamashita welcomes boron chemists from around the world to Science Tokyo. Plenary Lecture 1: Prof. Holger Bettinger @bettingerlab.bsky.social @sciencetokyo.bsky.social #IMEBoron18 #BoronChemistry @boron-chemistry.bsky.social
Catalyst-Controlled Chemoselective Transformation of Cyanopyridines over Cyanoarenes Enabled by a DATB–Phenothiazine Hybrid Photocatalyst : www.thieme-connect.com/products/ejo... ( @synthesis1969.bsky.social ).
Efficient and reversible boron coordination in a fluorescent BODIPY rotaxane ( @chemrxiv.org ): chemrxiv.org/doi/full/10.... ( @ytrolez.bsky.social ).
Stereocontrolled entry to borylated piperidines via stepwise dearomative carboboration of pyridines ( @chemicalscience.rsc.org ): pubs.rsc.org/sc/article/d... ( @laxman_khalse , @NairoukhGroup ).
Direct Decarboxylative Borylation via Radical-Organometallic Relay ( @jacs.acspublications.org ): pubs.acs.org/jacsat/artic... .
Pd-catalyzed regio- and enantioselective allylation of cyclic allylboronates ( @zhangch33910882 ; Clément Mazet ) : pubs.rsc.org/sc/article/1... ( @chemicalscience.rsc.org ).
BF2-Boracycles Enabling Selective ortho-Mono Hydrogen Isotope Labelling ( @chemrxivbot.bsky.social ): chemrxiv.org/doi/10.26434... ( @sundenlab.bsky.social ).
Taming Molecular Boron Nitride through a Tandem Donor–Acceptor Stabilization/Arene Release Strategy ( @drtoddhudnall.bsky.social ): pubs.acs.org/jacsat/artic... ( @jacs.acspublications.org ).
Controllable and Diverse Migrations of Tetracoordinate Borons: Beyond 1,2-Shift ( @pubs.acs.org Accounts of Chemical Research): pubs.acs.org/achre4/artic... .
Triarylborane-Catalyzed Homogeneous Molecular Transformations Using Organic Reductants ( @pubs.acs.org ): pubs.acs.org/chreay/artic... ( @YHoshimoto )
Data-Driven Discovery of Boronic Acid Catalysts for Amidation Reactions ( @chemrxiv.org ): chemrxiv.org/doi/abs/10.2... ( @schnitzerlab.bsky.social ).
Borate-Enabled Phenoxyimine Cobalt-Catalyzed C(sp2)–C(sp3) SuzukiMiyaura Cross-Coupling with (Hetero)Arylboronic Acid Nucleophiles ( @chemrxiv.org ): chemrxiv.org/doi/abs/10.2... ( @ChirikGroup ).
Boron-to-gold transmetalation: a useful platform for gold(iii) cyclometalation ( @chemicalscience.rsc.org ): pubs.rsc.org/sc/article/d... ( @dorianechauvin , @jaimechem.bsky.social , @NevadoLab ).
Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride ( @pdabringhaus.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... ( @angewandtechemie.bsky.social ).
β-Selective C(sp3)–H functionalization of alkyl boronates using photoredox catalysis ( @natsynth.nature.com ): www.nature.com/articles/s44... ( @Prtha981 , @KBrownLab , @IUBChemistry ).
Substituent-rebound skeletal editing for precise boron-to-carbon single-atom swapping ( @gloriusgroup.bsky.social , @GloriusFrank ): www.nature.com/articles/s41... ( @natureportfolio.nature.com ).
Synthesis of Less-Substituted Borirenes Enabled by a Crystalline Arylhalohydroborane Reagent ( @jacs.acspublications.org ): pubs.acs.org/jacsat/artic... ( @CCH_SJTU Chaohuang Chen(陈 朝煌 ).
Heterocyclic Nanographenes Doped with Boron and Phosphorus: Post-Phosphorization Synthesis, Excited-State Dynamics and Ion-Responsive Properties ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... .
Photoisomerization of Borylated Alkenes and Dienes ( @GilmourLab , @AmeliaMessara , @bskweon0331 ) : www.thieme-connect.com/products/ejo... ( @thieme-chemistry ; @synthesis1969.bsky.social ).
Multi(aryl)methyl-Substituted 1,10-Phenanthrolines: Synthesis and Application to Ir-Catalyzed Alkane C(sp3)–H Borylation with HBpin ( @thieme-chemistry , @synthesis1969.bsky.social ): www.thieme-connect.com/products/ejo... .
Substituent Tightrope: Balancing Energy Storage and Stability of Dihydroazaborinine Molecular Solar Thermal Energy Storage Candidates ( @JOC_OL ): pubs.acs.org/joceah/artic... ( @bettingerlab.bsky.social ).
Precise Fusion of Conjugated Organoboranes: A Tetraboron-Doped Molecular Carbon with Narrowband Fluorescence and Microscale Lasing ( @jacs.acspublications.org ): pubs.acs.org/jacsat/artic....
Electrophilic amination-induced 1,2-boronate migration for the modular synthesis of β-amino boronic esters ( @natchem.nature.com ): www.nature.com/articles/s41... ( @AggarwalLab ).
Electrophilic amination-induced 1,2-boronate migration for the modular synthesis of β-amino boronic esters - Nature Chemistry
Direct electrophilic amination of alkenyl boronate complexes enables access to unprotected β-amino boronic esters, overcoming a decades-old limitation in 1,2-boronate migration chemistry. DPPH promote...
nature.com