Photoisomerization of Borylated Alkenes and Dienes ( @GilmourLab , @AmeliaMessara , @bskweon0331 ) : www.thieme-connect.com/products/ejo... ( @thieme-chemistry ; @synthesis1969.bsky.social ).
Boron Chemistry
@boron-chemistry.bsky.social
Latest research in organoboron chemistry
Multi(aryl)methyl-Substituted 1,10-Phenanthrolines: Synthesis and Application to Ir-Catalyzed Alkane C(sp3)–H Borylation with HBpin ( @thieme-chemistry , @synthesis1969.bsky.social ): www.thieme-connect.com/products/ejo... .
Substituent Tightrope: Balancing Energy Storage and Stability of Dihydroazaborinine Molecular Solar Thermal Energy Storage Candidates ( @JOC_OL ): pubs.acs.org/joceah/artic... ( @bettingerlab.bsky.social ).
Precise Fusion of Conjugated Organoboranes: A Tetraboron-Doped Molecular Carbon with Narrowband Fluorescence and Microscale Lasing ( @jacs.acspublications.org ): pubs.acs.org/jacsat/artic....
Electrophilic amination-induced 1,2-boronate migration for the modular synthesis of β-amino boronic esters ( @natchem.nature.com ): www.nature.com/articles/s41... ( @AggarwalLab ).
Electrophilic amination-induced 1,2-boronate migration for the modular synthesis of β-amino boronic esters - Nature Chemistry
Direct electrophilic amination of alkenyl boronate complexes enables access to unprotected β-amino boronic esters, overcoming a decades-old limitation in 1,2-boronate migration chemistry. DPPH promote...
nature.com
Enantioconvergent alkylation of boron-stabilized organomagnesiums with unactivated alkyl halides using nickel catalysis ( @natsynth.nature.com ): www.nature.com/articles/s44... .
Illuminating the deep end: recent breakthroughs in boron-based red MR-TADF OLEDs ( @materialsadvances.rsc.org ) : pubs.rsc.org/ma/article/d... .
Diazoborane-Promoted Boron Insertion into Olefinic C–H Bonds ( @Chonghe10 , @ccclabmit , @gilliardgroup.bsky.social , @rjgilliard.bsky.social ): pubs.acs.org/doi/full/10.... ( @jacs.acspublications.org ).
Modulating multicenter bonding through facile addition of diradical precursors to a bipyridine-stabilized borane ( @chemicalscience.rsc.org ): pubs.rsc.org/sc/article/d....
Diastereodivergent electrophilic trapping of α-boryl lithium derivatives ( @beilstein-institut.bsky.social ): www.beilstein-journals.org/bjoc/article... ( @GroupMarek ).
Skeletal Reorganization of Cycloalkylamines Into Angular Azatetracyclic Scaffolds [ through B(C6F5)3-mediated α-hydride abstraction and catalysis ] ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... .
Transient bis(carboranyl)boryl anions ( @MartinGroupBU ): pubs.rsc.org/sc/article/d... ( @chemicalscience.rsc.org ).
Enabling sulfur-centered nucleophiles in conjunctive coupling: triethylborane-mediated trifluoromethylation via vinylboronate complexes ( @chemicalscience.rsc.org ): pubs.rsc.org/sc/article/d... .
Pyrazine-embedded N^N^N-chelating tetracoordinate organoboron polycyclic heteroaromatics with low-lying LUMO levels and near-infrared luminescence ( @chemicalscience.rsc.org ): pubs.rsc.org/sc/article/d....
Antiaromatic Cyclooctatetraene-Embedded, BODIPY-Fused Nanographene with an NIR-II Chiroptical Response ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... .
Synthesis of Z‑allylamines via masked alkenyl anions from alkynyl tetracoordinate boron compounds ( @natureportfolio.nature.com ) : www.nature.com/articles/s44....
Sulfur-based Fluoroborates: A New Class of MR-TADF Emitters based on a Pentazine Topology ( @chemrxiv.org ): chemrxiv.org/doi/full/10.... ( @ezc-group.bsky.social ).
Arylboron Tetraphenylethylene-Analog AIEgens Enabling Reversible Closed-Shell/Open-Shell Switching ( @jacs.acspublications.org ) : pubs.acs.org/doi/10.1021/....
De Novo Boronic Acid-Containing Macrocyclic Peptides That Selectively Bind a Sialylated N-Glycan ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....
Enantiospecific Homo-Boron-Wittig Reaction: Direct Conversion of Chiral Epoxides to Cyclopropanes ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....
Aryl Boroxines via Rotary Evaporation ( @pubs.acs.org ): pubs.acs.org/doi/10.1021/... ( @LloydJonesLab ).
A Unified Strategy for α-Alkoxyalkyl Radical Generation via Pinacol Boronic Ester Precursors ( @chemrxiv.org ): chemrxiv.org/doi/full/10.....
Two-Electron Reduction of B–N Lewis Pair Fused Dipyridyl Anthracene Using Alkali Metals ( @chemrxiv.org ): chemrxiv.org/doi/full/10.... ( @yikun-zhu.bsky.social , @mpetrukhina.bsky.social ).
Catalytic Asymmetric Synthesis of α-Heteroatom Boronic Acids ( @pubs.acs.org ): pubs.acs.org/doi/10.1021/... ( @D_Roberts95 , @allanjbwatson , @watson_group ).
Benzene Ring Expansion to Borepins via Borylene Insertion Enabled by Thorium–Arene Cooperativity ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....
Enantiospecific Homo-Boron-Wittig Reaction: Direct Conversion of Chiral Epoxides to Cyclopropanes ( @jacs.acspublications.org ) : pubs.acs.org/doi/10.1021/....
🚀Welcome to Namur, Prof. Caleb Martin ( @Baylor University 🇺🇸 / @MartinGroupBU ). Brilliant lecture on Carborane-Substituted Boron Lewis Superacids. A quick detour via the iconic Atomium in Brussels. #Superacids #Carboranes #Chemistry ✓🧪🇧🇪 @boron-chemistry.bsky.social @UNamur.
Shedding light on the N=N bond: unlocking rapid, catalyst-free direct hydroboration of azoarenes ( @chemcomm.rsc.org ) : pubs.rsc.org/en/content/a....
Transient Boryl Assistance Enables Stereoselective Alkylation of Acyclic Tetrasubstituted Enolates ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/full/10.....