Visible Light-Mediated Dearomative Cyclopropanation of Benzoheterocycles via 3-exo-trig Radical Cyclization

Abstract. Fused cyclopropanes are prominent motifs in bioactive molecules, yet their incorporation into densely functionalized frameworks remains a signifi

doi.org

Visible Light-Mediated Dearomative Cyclopropanation of Benzoheterocycles via 3-exo-trig radical cyclization | ChemRxiv

Fused cyclopropanes are prominent motifs in bio-active molecules, yet their incorporation into densely functionalized frameworks remains a significant synthetic challenge. Herein, we report a light-mediated dearomative cyclopropanation of ben-...

chemrxiv.org

Visible‐Light Mediated Activation of 1,3‐Dienes and Allenes via Energy Transfers

Nature has inspired chemists to develop photocatalytic processes that harness visible light, offering alternative reaction pathways beyond traditional thermal methods. Energy Transfer (EnT) is a part....

chemistry-europe.onlinelibrary.wiley.com

Light-Mediated Binaphthyl Enhanced [2 + 2] Dearomatization of Heterocycles via an Energy-Transfer Process

Three-dimensional heterocycles are crucial in medicinal chemistry, yet efficient methods for their preparation remain limited. We report a light-mediated [2 + 2] dearomatization strategy for simple an...

pubs.acs.org

Visible‐Light Promoted Intramolecular para‐Cycloadditions on Simple Aromatics

We present the first synthesis of bridged bicycles through the dearomatization of sterically and electronically unbiased aryl fragments. The visible-light promoted method occurs at room temperature a...

onlinelibrary.wiley.com

Tuning the Efficiency of Iridium(III) Complexes for Energy Transfer (EnT) Catalysis through Ligand Design

A family of heteroleptic Iridium(III) complexes, which can act as Energy Transfer (EnT) photocatalysts, has been prepared and tested in photochemical transformations. Our study explores ligand design...

chemistry-europe.onlinelibrary.wiley.com