Robert Hein

@robertheinchem.bsky.social

Juniorprofessor @uni-muenster.de, Prior: MSCA Postdoc @feringalab.bsky.social, PhD @ox.ac.uk, Supramolecular Chemistry, Electrochemistry, Sensors, Switches https://www.uni-muenster.de/Chemie.oc/hein/

Great project on the combined use of light- and redox-switching in hydrogels is now published in Nat. Commun. We can generate all types of stable redox patterns and actuation under ambient conditions using light for spatio-temporal control!

Dr. Roza@rozarehana.bsky.social · 10mo ago

Check out the most colourful work of my PhD, available now from Nature Communications! (It's open access, you have no excuse not to read) Thank you to my collaborators, among others @robertheinchem.bsky.social @feringalab.bsky.social www.nature.com/articles/s41...

Just returned from an awesome 3-week lecture/conference tour in Japan🗾 with stops in Kyoto, Fukuoka, Hiroshima, Osaka and Nagoya. Had an amazing time with great food, awesome people and inspiring science! Arigato gozaimasu!

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Just published in @jacs.acspublications.org, our project @feringalab.bsky.social on responsive crown ethers! Redox-switching? Light-switching? Why not both and get the best of all worlds, including guest shuttling, pseudorotaxanes, cascades and (non)volatile states. pubs.acs.org/doi/10.1021/...

Multi-State Redox and Light-Driven Switching of Pseudorotaxanation and Cation Shuttling

The modulation of molecular recognition underpins numerous wide-ranging applications and has inspired the development of a myriad of switchable receptors, in particular photo- or redox-responsive hosts. Herein, we report a highly versatile three-state cation receptor family and switch system based on an overcrowded alkene strapped with crown ethers, which can be switched by both redox and light stimuli, thereby combining the advantages of both approaches. Specifically, the neutral switches can be quantitatively converted between anti- and syn-folded receptor geometries by irradiation, leading to the discovery of a significant increase or decrease in cation binding affinity, which was exploited to shuttle the pseudorotaxane-forming dibenzylammonium guest between the switchable crown ethers of slightly different sizes. Alternatively, two-electron oxidation to the orthogonal, dicationic, nonvolatile state completely turns off cation binding to the host, thereby ejecting the guest. Upon reduction, the metastable syn-folded state is first formed, which then thermally relaxes, resulting in a unique, autonomous, and cation-dependent multistate switching cascade.

pubs.acs.org