Our new perspective on proton-coupled electron transfer (PCET) reactions is finally out: doi.org/10.1002/anie...
Katja Heinze's research group University of Mainz
@labheinze.bsky.social
loves transition metal complexes: photophys | photochem | redox | catalysis | spectroscopy | sustainable chemistry | unsolved problems @uni_mainz www.ak-heinze.chemie.uni-mainz.de
Need a primer on 𝗵𝗼𝘄 𝘀𝗽𝗶𝗻𝘀 𝗱𝗲𝗽𝗼𝗹𝗮𝗿𝗶𝘇𝗲 𝗶𝗻 𝗵𝗮𝗹𝗶𝗱𝗲 𝗽𝗲𝗿𝗼𝘃𝘀𝗸𝗶𝘁𝗲 𝘀𝗲𝗺𝗶𝗰𝗼𝗻𝗱𝘂𝗰𝘁𝗼𝗿𝘀 and how to detect this? We got you covered! Check out our latest review led by Huygen in 𝗖𝗛𝗜𝗠𝗜𝗔 (by SCS) as part of the special issue on chiral light-matter interactions:) open-access here: www.chimia.ch/chimia/artic...
Covalency control of photomagnetic relaxation in a manganese(II) photoswitch #chemsky
Covalency control of photomagnetic relaxation in a manganese(II) photoswitch
Nature Chemistry, Published online: 29 June 2026; doi:10.1038/s41557-026-02193-8Light-induced excited spin state trapping (LIESST) has largely been limited to iron complexes and typically requires cryogenic temperatures or large nuclear rearrangements, limiting practical photomagnetic switching. Now a carbene manganese(II) complex achieves LIESST at 141 K in solution, demonstrating that increased metal–ligand covalency and rigidity can stabilize long-lived high-spin states and extend photomagnetic switching towards more practical temperature regimes.
dlvr.it
Forschende im @labheinze.bsky.social der #UniMainz erzielen Durchbruch in der Spintronik: Neues molekulares Material auf Manganbasis ermöglicht Datenspeicherung bei höheren Temperaturen 👉 presse.uni-mainz.de/spinzustaende… #Spintronik #Mangan #Photochemie #Photoreaktion #Chemie
Research team of #MainzUniversity achieves a breakthrough in spintronics: New manganese-based molecular material enables data storage at higher temperatures 👉 press.uni-mainz.de/switching-spi… #spintronics #mangan #photochemistry #photoreaction #chemistry
Link: doi.org/10.1002/anie...
Circularly Polarized Luminescent and Melt‐Processable Copper(I)‐Organic Glasses Based on 2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl
Homochiral Cu(I) cyanide complexes based on 2,2’-bis(diphenylphosphino)-1,1’-binaphthyl (BINAP) form melt-quenched and desolvation-derived metal–organic glasses that exhibit circularly polarized ther...
doi.org
The 30th @gdch.de Photochemistry conference (LCP) is approaching and will take place in beautiful Braunschweig in September. It includes five plenary lectures by well-respected speakers, as well as two prestigious award lectures. Visit www.gdch.de/photo2026 for further details.
The CRC 1633 recently met at Hofgeismar for our yearly retreat, bringing together all research groups to discuss current projects, strengthen collaboratoins, and explore new ideas. Many thanks to our keynote speakers, Prof. Reinhard Maurer and @winald-kitzmann.bsky.social!
Matthias' paper with a thorough investigation of a Coulombic Dyad has been published in Chem. Phys. Rev. as a part of the "70 Years of Dexter Energy Transfer" collection. Many thanks also to our collaborators from the @labheinze.bsky.social and Diezemann groups). #Photochemistry #EnergyTransfer
Happy to share this amazing work from Dilara @univie.ac.at, together with Dwyne Miller‘s group @utoronto.ca, just out at @angewandtechemie.bsky.social 🔥🔥🔥🔥🔥 #SHARC 🦈 SCO dynamics with #RASSCF in a Fe(III) open-shell complex & transient spectroscopy 🧪⌨️💡 onlinelibrary.wiley.com/doi/10.1002/...
Elucidating the Transition Kernel and Anharmonic Coupling in the Spin‐crossover Process of a [FeIII(qsal)2] CH3OSO3 Complex
Ultrafast broadband transient absorption spectroscopy and multireference excited-state nonadiabatic calculations in an open-shell Fe(III) complex unveil the rich electronic and vibrational dynamics d...
onlinelibrary.wiley.com
2026 marks 90 years of [Ru(bpy)₃]²⁺ which has undoubtedly shaped photochemistry since its inception. Celine Bourgois, @ludotroian.bsky.social and I took this opportunity to examine how this old system continues to fuel innovation in the field. Check it out here: pubs.acs.org/doi/10.1021/...
From PhD research to postdoctoral work, independent academic research, and experience in industry, three speakers bring a range of perspectives: Ask questions about career decisions, moving between academia/industry, research abroad, and building a career in chemistry in our next JuWöV session!
Singlet fission and spin-flip emission combined to demonstrate triplet harvesting of 130%. Now published in @jacs.acspublications.org. Thank you, Yoichi, for involving us. @mainzuniversity.bsky.social #spin-flip #molybdenum #singletfission #energytransfer
Exploring Spin-State Selective Harvesting Pathways from Singlet Fission Dimers to a Near-Infrared-Emissive Spin-Flip Emitter | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/...
We are welcoming oral contributions (15 min including discussion) and poster presentations for the 5th International Conference on Proton-Coupled Electron Transfer. More information can be found here: www.uni-goettingen.de/en/abstract+...
Abstract Submission - Georg-August-University Göttingen
Website of the Georg-August-University Göttingen
uni-goettingen.de
Klimafreundliche Gewinnung von Ameisensäure & Wasserstoff aus Abfallprodukt Glycerin: An #UniMainz entwickeltes Elektrolyseverfahren könnte wichtigen Beitrag zur Elektrifizierung der chemischen Industrie leisten 👉 presse.uni-mainz.de/klimafreundli… #Elektrolyse #NachhaltigeChemie #SusInnoScience
🎓 Bursary applications now OPEN for #ICCC2026 Support is available to help enable participation and broaden representation across the coordination chemistry community. Early-career researchers & students encouraged to apply. 👉 iccc2026.com #Bursaries #CoordinationChemistry
The first online symposium organized by the @gdch.de Division of Photochemistry will take place next week (Nov. 5, 2025, 3 pm CET zone). tu-braunschweig.webex.com/tu-braunschw... key: Photo2025 5 talks by talented students (one will be awarded🎉) followed by a plenary lecture. Save the date. ✍️
Super excited to see our work monitoring dynamics of the charge separated pair in a photocycle driven by a 2LMCT exited state now out in @chemicalscience.rsc.org ! ⚡️ Thanks for the great team efforts🌟 pubs.rsc.org/en/content/a...
Captivating bimolecular photoredox dynamics of a ligand-to-metal charge transfer complex
Transition metal complexes featuring ligand-to-metal charge transfer (LMCT) excited states have been identified as promising candidates for driving electron transfer processes. To obtain an efficient ...
pubs.rsc.org
Exploring metal-centered photoredox reactivity? 🚀Don’t forget to look at the spin-state landscape and the role of reorganisation energy, they can make a difference 😉 Huge thanks to Bekah for leading the experiments and shaping the story🥳 a true collaborative effort!😃 pubs.acs.org/doi/10.1021/...
Spin-State and Reorganization Energy Considerations for Metal-Centered Photoredox Catalysis
Transition-metal complexes featuring metal-centered excited states have recently emerged as mechanistically distinct platforms for selective photochemistry, including photoredox catalysis. Among these...
pubs.acs.org
Katja Heinze, Robert Naumann, and Steven Sittel (Mainz) synthesized a series of chromium(III) chromophores with identical optical properties but systematically tunable redox behavior to study photoredox mechanisms www.chemistryviews.org/independent-...
Design of Chromium(III) Chromophores with Independent Control of Redox and Optical Properties - ChemistryViews
Katja Heinze and Robert Naumann, Mainz, synthesized a series of chromium(III) chromophores with identical optical properties but systematically tunable redox behavior to study photoredox mechanisms
chemistryviews.org
Excited to share the publication of “Enhancing the Statistical Probability Factor in Triplet-Triplet Annihilation Photon Upconversion via TIPS Functionalization” in @chemicalscience.rsc.org pubs.rsc.org/en/content/a...
Very happy about this first #catalaix publication for us, supported by the Werner Siemens-Stiftung ! #bioplastics #circulareconomy We also make the data openly available at @radar-service.bsky.social : radar4chem.radar-service.eu/radar/en/dat... Thank you to @nfdi4chem.de !
New in Chemical Science! "Depolymerization of PLA Catalyzed by Guanidine-Modified Microgels" by Andrij Pich and Sonja Herres-Pawlis et al. from RWTH Aachen University and Maastricht University. @herreslab.bsky.social Read it for free: doi.org/10.1039/D5SC...
Thermally Activated and Nonactivated Excited State Decay of [Cr(dgpy)2]3+ | Inorganic Chemistry pubs.acs.org/doi/10.1021/... @LabHeinze and co-workers @InorgChem #chromium #aliphatic #guanidines #thermally_activated_nonactivated #EnT #bISC #spin_flip #VibrationalOvertones #NIR
Die GDCh schließt sich dem Klimaaufruf von DPG und DMG an: gdch.app/article/gdch...
GDCh schließt sich Klimaaufruf von DMG und DPG an.
Die Gesellschaft Deutscher Chemiker (GDCh) schließt sich dem gemeinsamen Aufruf der Deutschen Meteorologischen Gesellschaft (DMG) und der Deutschen Physikalischen Gesellschaft (DPG) an. „Globale Erwär...
gdch.app
So happy this piece is finally out! A tremendous collaborative effort of colleagues and friends from 8 institutions all over Europe. Thank you! doi.org/10.1038/s414... Photochemistry and photophysics in a single crystal @jagiellonskiuni.bsky.social @cleracr.bsky.social @natcomms.nature.com
We are looking for postdoctoral candidates in the areas of organic electronics, operando spectroscopy in catalysis, advanced EPR. CV and cover letter to slageren@ipc.uni-stuttgart.de, stating what complementary expertise you bring and why our group interests you.
Researchers at Johannes Gutenberg University Mainz report a manganese complex that stays energized for 190 ns after absorbing light—a record for low-cost abundant metals. cen.acs.org/materials/in... #chemsky 🧪
Manganese edges into the realm of noble-metal photochemistry
Pairing manganese with an off-the-shelf ligand yields a low-cost complex that mimics precious-metal photocatalysts
cen.acs.org
Common metal, unusual power: New manganese(I) complex breaks lifetime record for excited states / Combination of a #manganese salt and a ligand paves the way for future large-scale applications of #photochemistry 👉 press.uni-mainz.de/common-metal... #SustainableChemistry #SusInnoScience
From sub-picoseconds to 190 nanoseconds! Replacing #iron (II) by #manganese (I) gives record excited state lifetime. The paper in @natcomms.nature.com reports #coherence, #photoluminescence and excited state #electrontransfer. #earth-abundant metal plus simple #carbene #ligand. rdcu.be/eBWsL