Had a brilliant time representing the @bakewellgroup.bsky.social at @iccchemistry.bsky.social this week in Odense - some really brilliant chemistry going on! Lovely to see old friends and new there, some great chats! Big shout out too to @imosquire.bsky.social, a deserved poster prize winner!
Matt de Vere
@mattdv-t.bsky.social
PDRA, Bakewell Group at KCL (formerly: PDRA, Willcox Group, Manchester; PhD, Stasch Group, St Andrews). Main Group inorganic chemist, loves pretty crystals, sometimes posts pictures of food
Proud to have played a part in this! A great study!!
In our latest pre-print we show it’s possible to access a range of diphosphinoborane ligands with different substitutions on either the boron fragment or phosphine fragment. Congrats to Ryan, @mattdv-t.bsky.social and David. chemrxiv.org/doi/full/10....
Sharing for David: There’s a PhD studentship open in the Liptrot Group (@bathchem.bsky.social) - a great chance to get involved in some really exciting chemistry. Details here: www.findaphd.com/phds/project...
Cuprides – a Revolutionary Oxidation State of Copper at University of Bath on FindAPhD.com
PhD Project - Cuprides – a Revolutionary Oxidation State of Copper at University of Bath, listed on FindAPhD.com
findaphd.com
Nice to see @daltontrans.rsc.org have deemed this paper from my PhD work a "HOT article"! 🥵🥵 pubs.rsc.org/en/content/a...
Synthesis of heteroleptic calcium amide complexes via manipulation of the Schlenk equilibrium
Heteroleptic calcium β-diketiminate (BDI) complexes have been recognised as potent (pre)catalysts for a variety of transformations and have demonstrated valuable stoichiometric reactivity. Bulky ligands such as BDIs have been utilised to prevent unwanted dismutation and decomposition reactions of active hete
pubs.rsc.org
Had a great time in Edinburgh at the RSC Main Group AGM this week! Some fantastic talks and posters, great company, and it was nice to get a chance to present the work we've done on our aluminium(I) trimer as well! (Shout out to my official photographer @michi-tritto.bsky.social)
Thank you for the write up @chemistryworld.com - an honour to have our work included in such great company!
These are exciting times for aluminium chemistry.
Sir James Dewar, Scottish chemist, would be nominated for the Nobel 8 times, but you probably know him for his most famous invention, which never made him a penny, developed to hold ultra-cold liquified gases. You probably own a "Dewar vessel," but you know it as a Thermos™. Let's talk about it.
a person is holding a container over their head in a kitchen ..
Alt: a person is holding an insulated container of liquid nitrogen. They pour the liquified gas over an open human hand in a lab setting. The Leidenfrost effect prevents any serious injury, as the liquid boils off before transferring much heat.
media.tenor.com
Check out the new @bakewellgroup.bsky.social paper, published in @daltontrans.rsc.org! A real labour of love for me, when I turned up Clare asked me to "make a few more ligands", advice I took and ran with. See inside for all you could ever wish to know about making bulky amidine ligands...
Amidines: a deeper look at the archetypal pro-ligand
Amidinates ([R1NC(R2)NR3]−) are versatile and ubiquitous ligands in inorganic and main group chemistry, due to their anionic, bidentate nature and easy tunability. Herein we present the synthesis of 2...
pubs.rsc.org
Registration deadline for the RSC main group meeting and AGM 16th March! There’s a great line up of speakers and poster abstract submission still open - come and join us in Edinburgh!
Registration is now open for the 2026 RSC (@rsc.org) Main Group Interest Group Conference: www.rsc.org/events/detai... The meeting will be taking place on the 8-9th April 2026 at the University of Edinburgh, showcasing a breadth of inorganic/main group chemistry- We would love to see you there.
FAO Main Group chemists here on bluesky - a while ago I made a list of all of you, it makes for an excellent Main Group-focused timeline. If you want to add it just click on the list and pin it! Also, if I'm missing anyone just let me know! #chemsky #realtimechem #chemchat #maingroup
The first isolation of neutral aluminium(i) trimers called cyclotrialumanes is reported by Bakewell et al. in @natcomms.nature.com. CSD Entry OXATOA reveals a perfectly planar Al₃ ring, supported by a bulky amidinate framework. 🔗 dx.doi.org/10.5517/ccdc... #FeaturedStructureFriday #CompChemSky
Minor life ambition achieved today!
The first isolation of neutral aluminium(i) trimers called cyclotrialumanes is reported by Bakewell et al. in @natcomms.nature.com. CSD Entry OXATOA reveals a perfectly planar Al₃ ring, supported by a bulky amidinate framework. 🔗 dx.doi.org/10.5517/ccdc... #FeaturedStructureFriday #CompChemSky
I am excited to announce a fully-funded PhD Scholarship in Molecular Bismuth Chemistry (and beyond) is now available in our research group at Flinders University. Advertisement: lnkd.in/g4T8JJ_U Group Website: isolobal.com #PhDPosition #OrganometallicChemistry #ChemistryResearch #PhDOpportunity
For some background (or a potted summary) check out my "behind the paper" blog post, available here: communities.springernature.com/posts/a-neut...
A neutral cyclic aluminium (I) trimer
Monomeric, dimeric and tetrameric aluminium(I) neutral complexes have all been previously reported, but a trimeric species has never previously been observed. We present the first trimeric neutral alu...
communities.springernature.com
Absolutely thrilled to see our ( @bakewellgroup.bsky.social ) paper "A neutral cyclic aluminium (I) trimer" has been published in @natcomms.nature.com in its full typeset version! www.nature.com/articles/s41...
Absolutely thrilled to see our ( @bakewellgroup.bsky.social ) paper "A neutral cyclic aluminium (I) trimer" has been published in @natcomms.nature.com in its full typeset version! www.nature.com/articles/s41...
A neutral cyclic aluminium (I) trimer - Nature Communications
Low oxidation state aluminium complexes have gained wide recognition as discrete and versatile 2-electron reductants, but neutral trimeric structures remain elusive. Here the authors report the synthe...
nature.com
Just incredible work, huge congratulations to Liu and Zhang, spectacular! Aluminium redox catalysis enables cyclotrimerization of alkynes | Nature share.google/zhTlJiO9CJLv...
Aluminium redox catalysis enables cyclotrimerization of alkynes - Nature
Aluminium redox catalysis is achieved with a low-valent aluminium species, carbazolylaluminylene, enabling cyclotrimerization of alkynes and producing diverse benzene derivatives.
share.google
First paper of the year and a wonderful collaboration with the @millsgroupchem.bsky.social. Congrats to Jake and the team for the mammoth effort. chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
Unusual Reactivity of a Heterobimetallic Al─Zn Complex With a Carbodiimide
We show that subtly changing steric bulk about the Al─Zn bonds of heterobimetallic complexes can switch on reactivity with heteroallenes at the aluminium-pentamethylcyclopentadienyl moiety as well as...
chemistry-europe.onlinelibrary.wiley.com
Registration is now open for the 2026 RSC (@rsc.org) Main Group Interest Group Conference: www.rsc.org/events/detai... The meeting will be taking place on the 8-9th April 2026 at the University of Edinburgh, showcasing a breadth of inorganic/main group chemistry- We would love to see you there.
RSC Main Group Interest Group Annual Meeting and AGM
GPE
rsc.org
Really cool chemistry! Amidine ligands with the magic touch it seems 👀 #chemsky
FINALLY a complex of type LMg-CaL! This formally Mg(0)-Ca(II) complex shows a very long Mg-Ca bond with Mg(-)/Ca(+) polarization and is quite reactive! Our first 2026 paper is "In dear memory of Herbert Roesky" shorturl.at/tvi0C
I am advertising a fully funded chemistry PhD scholarship in my group at @aucklanduni.bsky.social to study titanium catalysts attached to sold supports. For more details see: tinyurl.com/FalconerPhD1 Please repost and share! #chemsky #inorganicchemistry #PhD #PhDscholarship #catalysis #greenchem
#phd #catalysis #scholarship #chemistry #universityofauckland | Rosalyn Falconer
PhD Opportunity – Fully Funded Scholarship in Titanium Catalysis A fully funded PhD scholarship is available to join the Falconer Group at the University of Auckland. This project will focus on titan...
tinyurl.com
Got to help the new PhD student with their first crystals yesterday, although I did have to point out they probably won't see diffraction quite like this every time they grow crystals! #chemsky
We're Hiring! If you are interested in a PDRA post with the Mehta group, please apply! @ox.ac.uk @oxfordchemistry.bsky.social my.corehr.com/pls/uoxrecru...
Job Details
my.corehr.com
The group will soon be advertising a 3-year PDRA position @imperialchemistry.bsky.social. The successful candidate will research the synthesis and reactivity of complexes with alkaline earth-metal bonds. Start date: 03/26. Please get in touch for infomal inquries.
A paper accepted late at the end of last year is this work with the Stasch group. We determined the structures of five calcium complexes, both homo- and heteroleptic, including a donor-solvent-free molecular calcium hydride complex. @standrewschem.bsky.social
Really pleased to see this work from my PhD in the Stasch group is (finally!) out in one of my favourite journals, @daltontrans.rsc.org! pubs.rsc.org/en/content/a...
Really pleased to see this work from my PhD in the Stasch group is (finally!) out in one of my favourite journals, @daltontrans.rsc.org! pubs.rsc.org/en/content/a...
Synthesis of heteroleptic calcium amide complexes via manipulation of the Schlenk equilibrium
Heteroleptic calcium β-diketiminate (BDI) complexes have been recognised as potent (pre)catalysts for a variety of transformations and have demonstrated valuable stoichiometric reactivity. Bulky ligan...
pubs.rsc.org
Hey #chemsky - NMR people! At King's we're hiring an NMR technical manager! Come join a lovely department and get to work with some fantastic chemists! www.kcl.ac.uk/jobs/134186-...
Technical Manager (NMR) | King's College London
kcl.ac.uk
And the molecule of the year for 2025 is...🥁... ...hexanitrogen! (I had a feeling this one would win 🤭) Thanks for voting, everyone! #chemsky cen.acs.org/synthesis/Mo...
Meet the molecules of the year 2025
C&EN editors’ annual round-up of spectacular molecules we’ve covered in the past year
cen.acs.org
We have the same problem! They keep tearing around the O-rings (and last barely 3 months max), never had this before now. Please, save us from this #chemsky
QUESTION TO THE COMMUNITY: Since COVID it is very difficult to get GOOD (STRONG) glovebox gloves. And they are very expensive! Any tips where to get normally priced good gloves? You can also direct-mail me: sjoerd.harder@fau.de Thanks for your advice!
One of the prettiest single crystals I think I've ever grown 🤩
The Mehta Group is recruiting a PhD student in Inorganic Synthesis and Catalysis. www.chem.ox.ac.uk/sitefiles/me... We are also taking on students through the iMAT CDT program! www.ox.ac.uk/admissions/g... If you are interested, apply!
chem.ox.ac.uk